1,10-Phenanthroline-5,6-dione CAS 27318-90-7 - Functional Ligand for Coordination and Materials Chemistry

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Author : Nina He
Update time : 2026-03-23 18:18:47

1,10-Phenanthroline-5,6-dione (CAS 27318-90-7) is a functionalized derivative of phenanthroline, widely used in coordination chemistry, analytical applications, and advanced materials research. Featuring two carbonyl groups at the 5 and 6 positions, this compound exhibits enhanced electron-accepting ability and versatile reactivity compared to unsubstituted phenanthroline.

 

Chemical Characteristics

1,10-Phenanthroline-5,6-dione typically appears as a yellow to orange crystalline solid. The presence of both nitrogen donor atoms and carbonyl functionalities allows it to act as a bidentate ligand with additional reactive sites. This unique structure enables strong coordination with transition metals such as copper, iron, and ruthenium, forming stable and functionally active complexes.

 

Applications

Coordination Chemistry

The compound is widely used as a ligand to form metal complexes with tunable electronic and redox properties. These complexes are studied for catalysis, electron transfer, and photochemical behavior.

 

Analytical Chemistry

Due to its ability to interact with metal ions and participate in redox reactions, 1,10-phenanthroline-5,6-dione is used in analytical methods for metal detection and chemical sensing.

 

Materials Science

It serves as a building block for advanced functional materials, including coordination polymers, electrochemical materials, and molecular devices.

 

Organic Synthesis

The diketone functionality allows further chemical modification, enabling the synthesis of more complex heterocyclic compounds and functional ligands.

 

Related Products

5,6-Diamino-1,10-phenanthroline (CAS: 168646-54-6)

5,6-Dimethyl-1,10-phenanthroline (CAS: 3002-81-1)

 

These derivatives provide additional options for coordination chemistry and functional material design, offering different electronic and steric properties for specific applications.

 

Supply Information

1,10-Phenanthroline-5,6-dione (CAS 27318-90-7) is available with high purity and consistent quality, suitable for research, development, and industrial applications. Reliable supply and flexible packaging options are available to meet diverse customer needs.

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