3,4,7,8-Tetramethyl-1,10-phenanthroline (CAS 1660-93-1): A Versatile Ligand for Advanced Applications

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Author : Nina He
Update time : 2026-04-20 18:16:46

In modern coordination chemistry and organic synthesis, 1,10-phenanthroline derivatives are widely recognized for their chelating ability and structural tunability. Among them, 3,4,7,8-Tetramethyl-1,10-phenanthroline (CAS: 1660-93-1) stands out as a highly effective ligand, offering enhanced electronic and steric properties for demanding applications.

 

With methyl substituents at the 3,4,7,8-positions, this compound exhibits increased electron-donating capability and steric hindrance compared to the parent phenanthroline structure. These modifications significantly improve its coordination strength with transition metals and enhance the stability of the resulting complexes. As a result, it is widely utilized in homogeneous catalysis, coordination material design, and advanced functional materials.

 

In catalytic systems, this ligand forms efficient complexes with metals such as copper, iron, and ruthenium, playing a key role in oxidation reactions, cross-coupling processes, and asymmetric catalysis. Its ability to fine-tune the electronic environment of metal centers also makes it a promising candidate in optoelectronic materials, including OLEDs and photochemical systems.

 

Beyond this compound, a range of structurally diverse phenanthroline derivatives are also available to meet different research and industrial needs:

 

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline (CAS: 4733-39-5), known for its excellent luminescent properties in organic electronics;

5,5'-Bi-1,10-phenanthroline (CAS: 96761-79-4), featuring dual coordination sites suitable for multinuclear complex construction;

1,3-Bis(9-phenyl-1,10-phenanthrolin-2-yl)benzene (CAS: 721969-94-4), widely applied in high-performance optoelectronic materials and coordination polymers.

 

These derivatives further expand the versatility of phenanthroline-based ligands, enabling tailored solutions across catalysis, materials science, and electronic applications.

 

UCHEM is capable of supplying this full range of phenanthroline derivatives, ensuring consistent quality and reliable delivery for both research and industrial-scale requirements. With strong expertise in fine chemicals and customized synthesis, UCHEM serves as a trusted partner for advanced chemical materials.

 

Overall, 3,4,7,8-Tetramethyl-1,10-phenanthroline represents a valuable building block in high-end chemical applications, with growing demand driven by ongoing innovation in catalysis and functional materials.

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