4,4'4,"-Tri-tert-butyl-2,2':6',2"-terpyridine (CAS 115091-29-7): A Sterically Tuned Terpyridine Ligand for Coordination Chemistry

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Author : Nina He
Update time : 2026-06-24 18:08:42

4,4'4,"-Tri-tert-butyl-2,2':6',2"-terpyridine (CAS: 115091-29-7) is a highly functionalized terpyridine derivative widely used in coordination chemistry, catalysis, supramolecular assembly, and advanced materials research. The introduction of three tert-butyl groups onto the terpyridine framework enhances solubility and steric properties while maintaining the excellent metal-chelating ability characteristic of terpyridine ligands.

 

Terpyridine compounds are among the most important nitrogen-containing ligands for transition metal complexation. Their tridentate coordination mode enables the formation of stable complexes with metals such as ruthenium, iron, cobalt, zinc, copper, and platinum. As a result, terpyridine derivatives are extensively employed in catalyst design, photochemistry, molecular recognition, and electronic materials development.

 

The bulky tert-butyl substituents in 4,4'4,"-Tri-tert-butyl-2,2':6',2"-terpyridine can influence both the electronic environment and steric accessibility around the metal center. These characteristics make the ligand particularly useful for tuning catalytic activity, improving material properties, and controlling supramolecular architectures.

 

In materials science, this compound is frequently investigated for applications in metal-organic assemblies, light-harvesting systems, molecular electronics, and coordination polymers. Its combination of strong coordination ability and enhanced solubility makes it a valuable building block for advanced functional materials.

 

With the continued growth of research in coordination compounds and energy-related materials, specialized terpyridine ligands remain essential tools for both academic and industrial innovation.

 

UCHEM supplies 4,4'4,"-Tri-tert-butyl-2,2':6',2"-terpyridine (CAS: 115091-29-7) with reliable quality and stable availability, supporting research and development projects worldwide.

 

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