5-Chloro-1,10-phenanthroline CAS 4199-89-7 - Functional Ligand for Coordination Chemistry

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Author : Nina He
Update time : 2026-03-26 18:05:05

5-Chloro-1,10-phenanthroline (CAS 4199-89-7) is a substituted phenanthroline derivative widely used as a ligand in coordination chemistry, catalysis, and materials science. The introduction of a chloro group at the 5-position enhances its reactivity and provides additional opportunities for further functionalization.

 

Chemical Characteristics

5-Chloro-1,10-phenanthroline typically appears as a light yellow to off-white crystalline solid. It retains the classic bidentate chelating structure of 1,10-phenanthroline, with two nitrogen atoms capable of coordinating strongly with transition metals such as copper, iron, ruthenium, and nickel.

 

The presence of the chloro substituent influences both the electronic and steric properties of the molecule, making it a versatile intermediate for designing modified ligands and functional materials.

 

Applications

Coordination Chemistry

This compound is widely used as a ligand to form stable metal complexes. These complexes are studied for their catalytic activity, redox behavior, and structural properties.

 

Catalysis

Metal complexes based on 5-chloro-1,10-phenanthroline are applied in various catalytic reactions, including oxidation, reduction, and cross-coupling processes.

 

Materials Science

It is used in the development of advanced materials such as luminescent complexes, electrochemical systems, and functional coordination polymers.

 

Organic Synthesis

The chloro group enables further derivatization through substitution reactions, making it a valuable intermediate for synthesizing more complex phenanthroline derivatives.

 

Supply Information

5-Chloro-1,10-phenanthroline (CAS 4199-89-7) is available with high purity and consistent quality, suitable for laboratory research, catalyst development, and materials science applications. Stable supply and flexible packaging options are available to meet different requirements.

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